Revisited Kinetic Chain Length and Reactivity Ratio Approaches for Linear Polymers and Copolymers

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Revisited Kinetic Chain Length and Reactivity Ratio Approaches for Linear Polymers and Copolymers

Two revisited mathematical kinetic relationships were derived, evaluated and applied on linear polymers such as polystyrene and copolymers such as (NIPAAm-alt-HEMA) and (MAAm-alt-HEMA) copolymers respectively. The validity of these equations was successfully verified. The first relationship, equation 12, interrelates exponentially kinetic chain length, average molecular weight and degree of pol...

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Synthesis and characterization of organotin containing copolymers: reactivity ratio studies.

Organotin monomers containing dibutyltin groups--dibutyltin citraconate (DBTC) as a new monomer and dibutyltin maleate (DBTM)--were synthesized. Free radical copolymerizations of the organotin monomers with styrene (ST) and butyl acrylate (BA) were performed. The overall conversion was kept low (< or = 15% wt/wt) for all studied samples and the copolymers composition was determined from tin ana...

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Symmetries of the Doi kinetic theory for nematic polymers of arbitrary aspect ratio: at rest and in linear flows.

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ژورنال

عنوان ژورنال: The Open Macromolecules Journal

سال: 2008

ISSN: 1874-3439

DOI: 10.2174/1874343900802010001